| 156029-03-7

• CAS: 156029-03-7
• 化学式: C₄₃H₂₈IN₂OW*I
• 分子量: 1026.37
• InChiKey: DPNRRFPBZSYCNM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四苯硼钠 以 乙腈 为溶剂， 生成 (CO)(2,2'-bipyridyl)bis(η2-1,4-diphenylbutadiyne)iodotungsten(II) tetraphenylborate
  参考文献：
  名称：

  1,4-Diphenylbutadiyne complexes of tungsten(II)

  摘要：

  Equimolar quantities of [WI2(CO)3(NCMe)2] and 1,4-diphenylbutadiyne (PhC2C2Ph) react in CH2Cl2 at room temperature to eventually give the iodo-bridged dimer [W(mu-I)I(CO)(NCMe)(eta2-PhC2C2Ph)]2 (1). Reaction of [WI2(CO)3(NCMe)2] with two equivalents of PhC2C2Ph eventually afforded [WI2(CO)(NCMe)(eta2-PhC2C2Ph)2] (2). The bimetallic 1,4-diphenylbutadiyne complex [W2I4(CO)2(NCMe)2(mu2,mu2'-eta2,eta2'-PhC2C2Ph)2] (3) was synthesized by reaction of equimolar quantities of 2 and [WI2(CO)3(NCMe)2]. The reactions of 1 and 2 with mono- and bidentate neutral donor ligands are also described.

  DOI：

  10.1016/0022-328x(94)80045-6
• 作为产物：
  描述：

  在 (C₅H₄N)2 作用下， 以 二氯甲烷 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  1,4-Diphenylbutadiyne complexes of tungsten(II)

  摘要：

  Equimolar quantities of [WI2(CO)3(NCMe)2] and 1,4-diphenylbutadiyne (PhC2C2Ph) react in CH2Cl2 at room temperature to eventually give the iodo-bridged dimer [W(mu-I)I(CO)(NCMe)(eta2-PhC2C2Ph)]2 (1). Reaction of [WI2(CO)3(NCMe)2] with two equivalents of PhC2C2Ph eventually afforded [WI2(CO)(NCMe)(eta2-PhC2C2Ph)2] (2). The bimetallic 1,4-diphenylbutadiyne complex [W2I4(CO)2(NCMe)2(mu2,mu2'-eta2,eta2'-PhC2C2Ph)2] (3) was synthesized by reaction of equimolar quantities of 2 and [WI2(CO)3(NCMe)2]. The reactions of 1 and 2 with mono- and bidentate neutral donor ligands are also described.

  DOI：

  10.1016/0022-328x(94)80045-6