[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,4-toluenedithiolate * CH2Cl2 | 403609-49-4

• 英文名称: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,4-toluenedithiolate * CH2Cl2
• CAS: 403609-49-4
• 化学式: CH₂Cl₂*C₂₉H₄₂FeP₂PdS₂
• 分子量: 763.932
• InChiKey: DYOBFFFOCHQDOQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲苯-3,4-二硫酚 、 二氯甲烷 、 Pd(dippf)Cl₂ 在 triethylamine 作用下， 以 二氯甲烷 为溶剂， 以56%的产率得到[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,4-toluenedithiolate * CH2Cl2
  参考文献：
  名称：

  Bidentate aryldichalcogenide complexes of [(diphosphino)ferrocene]palladium(II) and [(diphosphino)ferrocene]platinum(II). Synthesis, molecular structures and electrochemistry

  摘要：

  A series of homochalcogenide and mixed-chalcogenide ligand complexes of palladium and platinum have been prepared from the reactions of Pd(dppf)Cl-2, (dppf= 1,1'-bis(diphenylphosphino)ferrocene), Pd(dippf)Cl-2 (1, 1'-bis(diisopropylphosphino)ferrocene), and Pt(dppf)Ch with 1,2-benzenedithiol (HSC6H4SH) (a), 3,4-toluenedithiol (HSC6H3MeSH) (b), 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) (c), 2-mercaptophenol (HSC6H4OH) (d), thiosalicylic acid (HSC6H4CO2H) (e) and thionicotinic acid (HSC6H3NCO2H) (f). Single-crystal X-ray diffraction studies show that all complexes have distorted square-planar geometry. The complexes undergo two quasi-reversible or irreversible one-electron redox processes that involve the chalcogen ligands and diphosphinoferrocene ligands. The oxidation potentials of the chalcogen ligands increase when they bear electron-withdrawing substituents. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00923-8