deca(carbonyl)-bis(bis(tert-butyl)fluorophosphine) tri-osmium(0) | 165673-02-9

• 英文名称: deca(carbonyl)-bis(bis(tert-butyl)fluorophosphine) tri-osmium(0)
• CAS: 165673-02-9
• 化学式: C₂₆H₃₆F₂O₁₀Os₃P₂
• 分子量: 1179.11
• InChiKey: JACNFXMXRGGRGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(acetonitrile)decacarbonyltriosmium 、 叔丁基(二氟)膦 、 Di-tert-butylfluorphosphin 以 二氯甲烷 为溶剂， 以26%的产率得到deca(carbonyl)-bis(bis(tert-butyl)fluorophosphine) tri-osmium(0)
  参考文献：
  名称：

  tBu2PF as a ligand in tri-osmium clusters

  摘要：

  The reaction of (acetonitrile)-undeca(carbonyl)-tri-osmium(0) and bis(tert-butyl)fluorophosphine led to the formation of (bis(tert-butyl)fluorophosphine) undeca(carbonyl)-tri-osmium(0) (1). However, the reaction of bis(acetonitrile)-deca(carbonyl)-tri-osmium(0) and bis(tert-butyl)fluorophosphine yielded bis(bis(tert-butyl)fluorophosphine)-deca(carbonyl)-tri-osmium(0) (2) and (tert-butyl-difluorophosphine)(bis(tert-butyl)fluorophosphine)-deca(carbonyl)-tri-osmium(0) (3). Compounds 1 and 2 are the first aliphatic mono-fluorophosphine osmium clusters and were characterized by an X-ray diffraction study. Both compounds show a regular three-membered osmium cycle with equatorially oriented phosphorous atoms. Compound is 3 is the first example of a mixed mono-fluorophosphine-di-fluorophosphine compound and has been characterized by NMR spectra, a mass spectrum and an IR spectrum.

  DOI：

  10.1016/0022-328x(94)05375-l