1-(2-(1H-benzimidazol-2-yl)ethyl)pyridinium tetrafluoroborate | 136642-47-2

• 英文名称: 1-(2-(1H-benzimidazol-2-yl)ethyl)pyridinium tetrafluoroborate
• 英文别名: 1-<2-(1H-benzimidazol-2-yl)ethyl>pyridinium tetrafluoroborate；1-[2-(1H-benzimidazol-2-yl)ethyl]pyridinium tetrafluoroborate
• CAS: 136642-47-2
• 化学式: BF₄*C₁₄H₁₄N₃
• 分子量: 311.09
• InChiKey: INUSGNBIVLOEJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1-(2-(1H-benzimidazol-2-yl)ethyl)pyridinium tetrafluoroborate 以 乙醇 为溶剂， 反应 72.0h， 以70%的产率得到2-乙烯基-(9ci)-1H-苯并咪唑
  参考文献：
  名称：

  Synthesis of Dipolar Ethyleneimidazolium Benzimidazolate Inner Salts and Their Transformation to 2-Vinylbenzimidazoles through a Type of b-Elimination Reaction

  摘要：

  The synthesis and spectroscopic properties of the fairly stable title inner salts (5) are reported. For several of the betaines (5), both the highly dipolar character due to the terminal rings and the nature of the spacer promoted a type of beta-elimination reaction. Thus, formation of 2-vinylbenzimidazoles (7) from the corresponding betaines (5) proceeds in high yield under neutral and mild conditions. Following similar treatment, the 1-(2-benzimidazol-2-ylethyl)imidazolium salt (8b) undergo nucleophilic substitution reactions.

  DOI：

  10.3987/com-95-7294
• 作为产物：
  描述：

  吡啶 以 乙腈 为溶剂， 反应 8.5h， 生成 1-(2-(1H-benzimidazol-2-yl)ethyl)pyridinium tetrafluoroborate
  参考文献：
  名称：

  An efficient synthesis of 2-vinylbenzimidazoles from 1-(2-(benzimidazol-2-ylethyl)pyridinium salts using an anion-exchange resin

  摘要：

  Transformation of several 1-(2-benzimidazol-2-ylethyl)pyridinium salts, obtained by two different procedures, into their corresponding 2-vinylbenzimidazoles either using an anion-exchange resin (OH- form) or in the solid state is described. This approach now allows a facile entry into the almost unknown 2-vinylbenzimidazole monomers.

  DOI：

  10.1021/jo00023a013