Mo(CO)4(κ2-dipyrimidylamine) | 334977-57-0

• 英文名称: Mo(CO)4(κ2-dipyrimidylamine)
• 英文别名: Mo(CO)4(κ2-dipm)
• CAS: 334977-57-0
• 化学式: C₁₂H₇MoN₅O₄
• 分子量: 381.159
• InChiKey: OZBGHXFGEKGDIF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N-二(嘧啶-2-基)胺 、 molybdenum hexacarbonyl 以 甲苯 为溶剂， 以49%的产率得到Mo(CO)4(κ2-dipyrimidylamine)
  参考文献：
  名称：

  Dipyrimidylamine and tripyrimidylamine as chelating N-donor ligands

  摘要：

  Dipyrimidylamine (dipm) and tripyrimidylamine (tripm) are reported. A bidentate tripm ruthenium complex, [RuCl(eta (6)-p-cymene)(kappa (2)-tripm)]SbF6, is synthesized and structurally characterized. The presence of an intramolecular C-H . . .N hydrogen bond is proposed between the cymene C-H and a ring nitrogen in an uncoordinated pyrimidine ring. IR data on [Mo(CO)(4)(dipm)] suggest that the Tolman electronic parameter of the dipm ligand is similar to that of 2 x PPh3. M-L bonding may be weaker for pyrimidine versus pyridine because kappa (2)-tripm complexation is apparently more favorable relative to the kappa (3)-form than is the case for tripyridylamine. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00308-x