[Pd3Cl2[Ind(Ph2PS)2]2] | 1310823-92-7

• 英文名称: [Pd3Cl2[Ind(Ph2PS)2]2]
• CAS: 1310823-92-7
• 化学式: C₆₆H₄₈Cl₂P₄Pd₃S₄
• 分子量: 1483.43
• InChiKey: QFMYNPUKCFKMPK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 PdCl[1,3-bis(diphenylthiophosphinoyl)indene(-1H)] 在 polysterene-supported diisopropylethylamine 作用下， 以 二氯甲烷 为溶剂， 以86%的产率得到[Pd3Cl2[Ind(Ph2PS)2]2]
  参考文献：
  名称：

  1,3-Bis(thiophosphinoyl)indene: A Unique and Versatile Scaffold for Original Polymetallic Complexes

  摘要：

  The coordination of tridentate ligands featuring lateral coordination sites prone to acting as bridging ligands was explored with the aim of obtaining original polymetallic species in a straightforward and controlled manner. Accordingly, the 2-indenylidene chloropalladate [{Ind(Ph2P=S)(2)}PdCl](-) was found to behave as a kappa(2)-C,S bidentate ligand toward metal fragments, giving access to homo- and heteropolymetallic complexes. X-ray diffraction analyses reveal the presence of short metal metal contacts in all of these complexes. Density functional theory calculations unambiguously substantiate that the metals engage in unusual d(8)center dot center dot center dot d(8) interactions with a quasi-perpendicular arrangement of their coordination planes.

  DOI：

  10.1021/ic200842z