[2,5-bis(benzylaminothiocarbonyl)pyrrolyl-κ3-N1,S,S']bromonickel(II) | 1246009-63-1

• 英文名称: [2,5-bis(benzylaminothiocarbonyl)pyrrolyl-κ3-N1,S,S']bromonickel(II)
• CAS: 1246009-63-1
• 化学式: C₂₀H₁₈BrN₃NiS₂
• 分子量: 503.109
• InChiKey: ZXXMHUDQGLVGCE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-dibenzyl-1H-pyrrole-2,5-dicarbothioamide 、 nickel dibromide 以 乙醇 为溶剂， 以77%的产率得到[2,5-bis(benzylaminothiocarbonyl)pyrrolyl-κ3-N1,S,S']bromonickel(II)
  参考文献：
  名称：

  Nickel(II) complexes bearing a pincer ligand containing thioamide units: Comparison between SNS- and SCS-pincer ligands

  摘要：

  Nickel(II) complexes bearing a kappa(3)SNS pincer ligand, 2,5-bis(benzylaminothiocarbonyl)pyrrolyl (L1) and a kappa(3)SCS-pincer ligand, 2,6-bis(benzylaminothiocarbonyl)phenyl (L2), were synthesized, and their structures and electrochemical properties were elucidated. The crystal structures of [Ni(SNS)Br] (2) and [Ni(SCS)Br] (5) were determined by X-ray crystallography. The electrochemical and crystallographic data obtained from the complexes revealed that the kappa(3)SCS ligand has a stronger electron-donating ability than the kappa(3)SNS ligand. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.04.012