((η6-1,2,4,5-Me4C6H2)RuCl2(Cy2AsCH=CH2)) | 425643-70-5

• 英文名称: ((η6-1,2,4,5-Me4C6H2)RuCl2(Cy2AsCH=CH2))
• CAS: 425643-70-5
• 化学式: C₂₄H₃₉AsCl₂Ru
• 分子量: 574.471
• InChiKey: ODAWCWKEQQBUPL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ru(η(6)-durene)(μ-Cl)Cl]2 、 dicyclohexylvinylarsine 以 二氯甲烷 为溶剂， 以93%的产率得到((η6-1,2,4,5-Me4C6H2)RuCl2(Cy2AsCH=CH2))
  参考文献：
  名称：

  Synthesis and Characterization of [(η⁶-arene)RuCl₂(R₂AsCHCH₂)] and Tethered Arsinopropylarene−Ruthenium(II) Complexes

  摘要：

  The complexes [eta(6)-arene)RuCl2(R2AsCH=CH2)] [arene = MeC6H5, R = Ph (1a), R = Cy (1b); p-MeC6H4Me, R = Ph (2a), R = Cy (2b); o-MeC6H4Me, R = Ph (3a), R = Cy (3b); 1,3,5-Me3C6H3, R = Ph (4a); p-MeC6H4CHMe2, R = Ph (5a), R = Cy (5b); 1,2,4,5-Me4C6H2, R = Ph (6a), R = Cy (6b); C6Me6, R = Ph (7a)] have been synthesized by reacting [eta(6)-arene)-RuCl2](2) with the respective vinyl arsine. The compounds [eta(6)-MeC6H5)RuCl2(Ph2AsCH=CH2)] (1a) and [eta(6)-1,3,5-Me3C6H3)RuCl2(Ph2AsCH=CH2)] (4a) undergo KOBut-promoted intramolecular hydroalkylation in boiling acetonitrile to produce tethered arsinopropylareneruthenium(II) complexes 1c and 4c, respectively. The complexes have been characterized by H-1 and C-13{H-1} NMR spectroscopy, elemental analyses, cyclic voltammetry, and in several cases by X-ray crystallography.

  DOI：

  10.1021/om011092j