tris-(1'-(thiomethyl)ferrocenyl)phosphine | 615575-60-5

• 英文名称: tris-(1'-(thiomethyl)ferrocenyl)phosphine
• CAS: 615575-60-5
• 化学式: C₃₃H₃₃Fe₃PS₃
• 分子量: 724.338
• InChiKey: HQNRGKNFWOJLCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  正丁基锂 、 二甲基硫 、 tris-(1'-bromoferrocenyl)phosphine 以 乙醚 为溶剂， 生成 tris-(1'-(thiomethyl)ferrocenyl)phosphine
  参考文献：
  名称：

  The design and synthesis of a new potentially C3-symmetric ferrocenylphosphine

  摘要：

  A new potentially C-3-symmetric phosphine ligand 'manphos' has been obtained and fully characterized. The ligand which is a triferrocenyl-tetra-phosphine is obtained in a simple and effective two step synthesis starting from 1,1'-dibromoferrocene via the intermediate compound tris-(1'-bromoferrocenyl)phosphine or alternatively via 1'-bromo-1-diphenylphosphinoferrocene. The isopropylphosphino-analogue of manphos, tris-(1'-diisopropylphosphinoferrocenenyl)phosphine, has also been obtained, in addition to several functionalised derivatives of triferrocenylphosphine where the ferrocene rings have been substituted in the 1'-position. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00498-4