[Pd(6-(2,6-xylyl)-2,2'-bipyridyl)(Me)Cl] | 613666-75-4

• 英文名称: [Pd(6-(2,6-xylyl)-2,2'-bipyridyl)(Me)Cl]
• CAS: 613666-75-4；613232-92-1
• 化学式: C₁₉H₁₉ClN₂Pd
• 分子量: 417.246
• InChiKey: YNDICVXTPDYLSM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Pd(6-(2,6-xylyl)-2,2'-bipyridyl)(Me)Cl] 、 四(3,5-二(三氟甲基)苯基)硼酸钠 、 三苯基膦 以 二氯甲烷 为溶剂， 以66%的产率得到[Pd(6-(2,6-xylyl)-2,2'-bipyridyl)(PPh3)][B(3,5-(CF3)2C6H3)4]
  参考文献：
  名称：

  Reactivity of 6-(2-tolyl)- and 6-(2,6-xylyl)-2,2′-bipyridines with palladium(II) derivatives. Selective C(sp3)H vs. C(sp2)H activation

  摘要：

  Two new 6-substituted 2,2'-bipyridines, L, 6-(2-tolyl)bipy, L-1, and 6-(2,6-xylyl)bipy, L-2, have been synthesized. Their reactions with Na-2[PdCl4] or {Pd(OAc)(2)} afford either 1:1 adducts [Pd(L)X-2] (X = Cl, OAc) or five-membered cyclometallated derivatives [Pd(L-1-H)X] arising from C(sp(2))-H activation. From the chloro-alkyl intermediates [Pd(L)(Me)Cl], in the presence of Na[BAr4'] (Ar'=3,5-(CF3)(2)C6H3 cationic species [Pd(L)(Me)(S)](+) (L=L-1, L-2; S=CH3CN) can be obtained. At variance, in less coordinating solvents, e.g. dichloromethane, unexpected activation of a C(sp(3))-H bond occurs with loss of methane, to afford 6-membered cyclometallated derivatives. The latter species were isolated as [Pd(L-H)(PPh3)][BAr4']. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00457-1
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 6-(2,6-xylyl)-2,2'-bipyridine 以 乙醚 、 苯 为溶剂， 以87%的产率得到[Pd(6-(2,6-xylyl)-2,2'-bipyridyl)(Me)Cl]
  参考文献：
  名称：

  Reactivity of 6-(2-tolyl)- and 6-(2,6-xylyl)-2,2′-bipyridines with palladium(II) derivatives. Selective C(sp3)H vs. C(sp2)H activation

  摘要：

  Two new 6-substituted 2,2'-bipyridines, L, 6-(2-tolyl)bipy, L-1, and 6-(2,6-xylyl)bipy, L-2, have been synthesized. Their reactions with Na-2[PdCl4] or {Pd(OAc)(2)} afford either 1:1 adducts [Pd(L)X-2] (X = Cl, OAc) or five-membered cyclometallated derivatives [Pd(L-1-H)X] arising from C(sp(2))-H activation. From the chloro-alkyl intermediates [Pd(L)(Me)Cl], in the presence of Na[BAr4'] (Ar'=3,5-(CF3)(2)C6H3 cationic species [Pd(L)(Me)(S)](+) (L=L-1, L-2; S=CH3CN) can be obtained. At variance, in less coordinating solvents, e.g. dichloromethane, unexpected activation of a C(sp(3))-H bond occurs with loss of methane, to afford 6-membered cyclometallated derivatives. The latter species were isolated as [Pd(L-H)(PPh3)][BAr4']. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00457-1