N,N'-bis(2-hydroxy-3-tert-butylbenzaldimine)ferroceneamine titanium dichloride | 874534-19-7

• 英文名称: N,N'-bis(2-hydroxy-3-tert-butylbenzaldimine)ferroceneamine titanium dichloride
• CAS: 874534-19-7
• 化学式: C₃₂H₃₄Cl₂FeN₂O₂Ti
• 分子量: 653.267
• InChiKey: ZQDGQBDLWUOSRZ-YTPXGMBTSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofuran)titanium(IV) 、 N,N'-bis(2-hydroxy-3-tert-butylbenzaldimine)ferroceneamine 以 甲苯 为溶剂， 以66%的产率得到N,N'-bis(2-hydroxy-3-tert-butylbenzaldimine)ferroceneamine titanium dichloride
  参考文献：
  名称：

  The synthesis, coordination chemistry and ethylene polymerisation activity of ferrocenediyl nitrogen-substituted ligands and their metal complexes

  摘要：

  Treatment of aminoferrocene with substituted 2-hydroxybenzaldehydes yields the air- and moisture-stable ligands 1-4, which were then reacted to form the chromium dichloride complexes 5-7 and the nickel bis-chelate species 8 and 9. The metal compounds are very air-sensitive but the chromium compounds act as pre-catalysts for the polymerisation of ethylene. Reaction of 1,1'-bis(amino)ferrocene with similarly substituted 2-hydroxybenzaldehyes or simple benzaldehyde gives the ligands 10-12 and 17, respectively. The X-ray crystal structure of 11 shows the molecule to have non-crystallographic C-2 symmetry and to be linked by C-H-...pi interactions between the anthracene rings. Titanium-containing complexes 13-16 can be formed utilising ligands 10-12 and there is a change in geometry within the complexes dependent on the adjacent co-ligands, whilst ligand 17 can be reacted with PdClMe(COD) to form the chelate complex 18. Cyclic voltammetric studies have been carried out on 18 and its oxidised analogue 19, but both complexes are inactive towards ethylene polymerisation. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.051