[(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)RhCl]2 | 798547-93-0

• 英文名称: [(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)RhCl]2
• CAS: 798547-93-0
• 化学式: C₈₀H₇₂Cl₂O₂P₄Rh₂S₂
• 分子量: 1530.19
• InChiKey: YLUPOVFAEXRMPG-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  silver tetrafluoroborate 、 [(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)RhCl]2 以 二氯甲烷 为溶剂， 生成 [(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)Rh]2(BF4)2
  参考文献：
  名称：

  Halide-Induced Supramolecular Ligand Rearrangement

  摘要：

  A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented.

  DOI：

  10.1021/ja045316b
• 作为产物：
  描述：

  [(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)2Rh2(norbornadiene)]Cl2 以 二氯甲烷 为溶剂， 生成 [(4'-(2-Ph2PCH2CH2O)-4-(2-Ph2PCH2CH2S)biphenyl)RhCl]2
  参考文献：
  名称：

  Halide-Induced Supramolecular Ligand Rearrangement

  摘要：

  A novel reaction involving the halide-induced rearrangement of ligands within supramolecular Rh(I) complexes containing hemilabile ligands is presented. Three analogous bis- and trishemilabile ligands have been synthesized to construct bi- and trimetallic Rh(I) macrocyclic complexes. An intentionally added halide source results in the formal rotation of only one hemilabile ligand along the axis that is perpendicular to the plane defined by the aryl backbone of the hemilabile ligands. X-ray structures, as determined by X-ray crystallography, of key intermediates and products are presented.

  DOI：

  10.1021/ja045316b