Re(CC-2,5-di-n-hexyl-4-Me3SiCC-C6H2)(CO)3(N,N'-dimethylpiperazine) | 1147421-52-0

• 英文名称: Re(CC-2,5-di-n-hexyl-4-Me3SiCC-C6H2)(CO)3(N,N'-dimethylpiperazine)
• CAS: 1147421-52-0
• 化学式: C₃₄H₅₁N₂O₃ReSi
• 分子量: 750.083
• InChiKey: BLCULIMHUAUBON-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (2,5-dihexyl-4-iodophenylacetylide)(tricarbonyl)(N,N'-dimethylpiperazine)rhenium(I) 、 三甲基乙炔基硅 在 三乙胺 作用下， 以 甲苯 为溶剂， 以91%的产率得到Re(CC-2,5-di-n-hexyl-4-Me3SiCC-C6H2)(CO)3(N,N'-dimethylpiperazine)
  参考文献：
  名称：

  Synthesis of alkynyl(tricarbonyl)rhenium complexes containing a lightly coordinated diamine ligand

  摘要：

  Several alkynyl(tricarbonyl)diaminerhenium complexes were prepared from corresponding halo complexes and silver acetylides. With the diamine N,N'-dimethylpiperazine the compounds were found to be sufficiently stable to allow synthetic transformations on the acetylide ligand as well as purification by chromatography and subsequent substitution of the diamine ligand by stronger ligands such as phenanthrolines or isocyanides. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.07.031