[iridium(I)(1-(2-pyridyl)-2-(2,6-diisopropylphenyl)-2-aza-ethane)(1,5-cyclooctadiene)]Cl | 1101898-57-0

• 英文名称: [iridium(I)(1-(2-pyridyl)-2-(2,6-diisopropylphenyl)-2-aza-ethane)(1,5-cyclooctadiene)]Cl
• CAS: 1101898-57-0
• 化学式: C₂₇H₃₆IrN₂*Cl
• 分子量: 616.269
• InChiKey: JYTFTIBORBUXLC-PJERNYMYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 2,6-diisopropyl-N-(1-(pyridin-2-yl)ethylidene)aniline 以 二氯甲烷 为溶剂， 以99.5%的产率得到[iridium(I)(1-(2-pyridyl)-2-(2,6-diisopropylphenyl)-2-aza-ethane)(1,5-cyclooctadiene)]Cl
  参考文献：
  名称：

  Catalytic homogeneous CH-activation reactions of cyclooctane with [Ir(cod)LL]X complexes (LL=N,N-chelating ligands, amines, phosphines; X=Cl, PF6)

  摘要：

  A series of new [Ir(cod)LL]X complexes (LL = chelating ligands, amines, phosphines; X = Cl, PF6) was synthesized. The complexes catalyzed the selective homogeneous dehydrogenation of cyclooctane to give cyclooctene up to a rate of 61 turnovers. The activity and selectivity depends on the ligand structure of the corresponding coordination compound. The addition of external additives (amines and phosphines) increased the activities up to 100% in case of PCy3 and NHPh2. The dehydrogenation reaction showed a high temperature dependence. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2008.01.023