Si[(C3H6Si(Me)2-O-4-(2,5-C6H2Me2)-N=CH-2-Py)PtCl2]4 | 1006624-53-8

• 英文名称: Si[(C3H6Si(Me)2-O-4-(2,5-C6H2Me2)-N=CH-2-Py)PtCl2]4
• CAS: 1006624-53-8
• 化学式: C₇₆H₁₀₀Cl₈N₈O₄Pt₄Si₅
• 分子量: 2394.05
• InChiKey: IXNODUDZEYCJHG-QKYRRAHPSA-F

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 Si(C3H6Si(Me)2-O-4-(2,5-C6H2Me2)-N=CH-2-Py)4 以 二氯甲烷 为溶剂， 以74%的产率得到Si[(C3H6Si(Me)2-O-4-(2,5-C6H2Me2)-N=CH-2-Py)PtCl2]4
  参考文献：
  名称：

  Carbosilane dendrimers containing complexes N,N′-pyridylimine of molybdenum and platinum at their periphery

  摘要：

  Pyridylimine ligands of general formula CS-{O-4-(2,5-C6H2R2)-N=CH-2-Py}(n), where CS is a trimethylsilyl group (n = 1, R = H, Ia or Me, Ib) or a carbosilane dendritic framework (IIa,b, n = 4; IIIa, n = 8), have been coordinated to platinum(II) and molybdenum(O) centers to give the mononuclear [(Ia,b){PtCl2}], tetranuclear [(IIb){PtCl2}(4)] and [(IIb){Mo(CO)(3)(MeCN)}(4)], and octanuclear [(IIIa) {Mo(CO)(3)(MeCN)}(8)] complexes. The poor solubility of the polymetallic platinum compounds impedes the preparation of higher-generation dendrimers, although such a limitation is not found in the case of the more soluble molybdenum dendrimers. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.10.050