dichloro(η5-pentamethylcyclopentadienide)rhodium(III) | 1220917-88-3

• 英文名称: dichloro(η5-pentamethylcyclopentadienide)rhodium(III)
• CAS: 1220917-88-3
• 化学式: C₁₃H₂₄Cl₂O₃PRh
• 分子量: 433.117
• InChiKey: MIZDXXLIBQWHMC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 三(羟基甲基)磷化氢 以 二氯甲烷 为溶剂， 以71.2%的产率得到dichloro(η5-pentamethylcyclopentadienide)rhodium(III)
  参考文献：
  名称：

  New highly water-soluble rhodium complexes bearing 1,3,5-triaza-7-phosphaadamantane (PTA) and/or tris(hydroxymethyl) phosphine (THP)

  摘要：

  A family of cationic and neutral highly water-soluble rhodium complexes [Cp*Rh(PTA)(3)]Cl-2 (1), [Cp*RhCl2(THP)] (2), [Cp*RhCl(THP)(2)]Cl (3), and [Cp*RhCl(PTA)(THP)] Cl (4) have been synthesised and fully characterised [PTA = 1,3,5-triaza-7-phosphaadamantane; THP = tris(hydroxymethyl) phosphine]. Their water-solubility increases as the number of the phosphines coordinated to the metal centre is increased. The X-ray crystal structure of compound 2 was obtained and shows the presence of intermolecular hydrogen bonding. NMR speciation studies of [Cp*RhCl2(PTA)] in deuterated water show the existence of several equilibria involving substitution processes in which the water molecules can substitute both chloride and PTA ligands. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.041