dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]zink(II) | 872679-14-6

• 英文名称: dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]zink(II)
• CAS: 872679-14-6
• 化学式: C₂₀H₂₀Cl₂N₄Zn
• 分子量: 452.702
• InChiKey: HSBWWVKZTRBTKD-MEZAJFLCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,3-丁二酮 、 邻苯二胺 、 zinc(II) chloride 以 甲醇 为溶剂， 以55%的产率得到dichloro[1,4,7,10-tetraaza-5,6,11,12-tetramethyl-4,6,10,12-tetraene-2,3:8,9-dibenzylcyclodidecane]zink(II)
  参考文献：
  名称：

  Metal Ion Directed Synthesis of 12 and 14-Membered Tetraaza Macrocyclic Complexes and their Physico-Chemical Studies

  摘要：

  The template condensation reaction of o-phenylenediamine with 2,3-butanedione or 2,4-pentanedione resulted in the formation of new series of 12 and 14-membered tetraaza macrocyclic complexes: [ML1 Cl-2], [ML2 Cl-2] [M=Co(II), Ni(II) and Zn(II)]; [CuL1] Cl-2 and [CuL2] Cl-2. The formation of the macrocyclic framework and the overall geometry of the complexes have been characterized by elemental analyses, FT-IR, (HNMR)-H-1, UV-Visible, magnetic susceptibility and conductivity measurements. The copper( II) complexes exhibit square planar geometry, whereas an octahedral geometry is suggested for all other complexes.

  DOI：

  10.1081/sim-200067064