[Cu(2,2'-bipyridylamine)(p-aminobenzenecarboxylate)Cl] | 1042040-11-8

• 英文名称: [Cu(2,2'-bipyridylamine)(p-aminobenzenecarboxylate)Cl]
• CAS: 1042040-11-8
• 化学式: C₁₇H₁₅ClCuN₄O₂*H₂O
• 分子量: 424.346
• InChiKey: KPMKWIJMWCMLPP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-二吡啶胺 、 copper(II) choride dihydrate 、 水 、 对氨基苯甲酸 以 甲醇 、 水 为溶剂， 生成 [Cu(2,2'-bipyridylamine)(p-aminobenzenecarboxylate)Cl]
  参考文献：
  名称：

  Synthesis, structures and DNA binding of ternary transition metal complexes M(II)L with the 2,2′-bipyridylamine (L=p-aminobenzenecarboxylic acid, M=Ni, Cu and Zn)

  摘要：

  New ternary transition metal complexes of formulations [Ni(bpa)(p-AB)Cl](n) center dot 3nH(2)O (bpa = 2,2'-bipyridylamine, p-AB = aminobenzenecarboxylic acid) (1), [Cu(bpa)(p-AB)Cl] center dot H2O (2), [Zn(bpa)(p-AB)(2)] center dot H2O (3) are prepared, their structural features are characterized by crystal structural studies, and their DNA binding propensity has been evaluated by. fluorescence and viscosity method. In complex 2 and 3, both bpa and p-AB act as the bidentate N and O-donor ligand, respectively. While in complex 1, p-AB acts as a rare tridentate ligand. In the packing pattern of each complex, pi-pi interaction in their solid state is also described. The complexes show the competitive inhibition of ethidium binding to DNA, and the DNA binding propensity can be reflected as the relative order: 1 > 2 > 3. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.04.017