tricarbonyldibromo(N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine)molybdenum(II) | 155708-49-9

• 英文名称: tricarbonyldibromo(N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine)molybdenum(II)
• CAS: 155708-49-9
• 化学式: C₂₂H₂₂Br₂MoN₂O₅
• 分子量: 650.175
• InChiKey: YHSFBJRUAFFDPA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cis-tetracarbonyl(N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine)molybdenum(0) 在 Br₂ 作用下， 以 苯 为溶剂， 以51.7-57.6的产率得到tricarbonyldibromo(N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine)molybdenum(II)
  参考文献：
  名称：

  Aldimine derivatives of molybdenum carbonyl

  摘要：

  Aldimines (Ald) such as N,N'-bis(4-methylbenzylidene)-1,2-propanediamine (Ald1), N,N'-bis(4-methoxybenzylidene)-1,2-propanediamine (Ald2) or N,N'-bis(4-N,N-dimethylaminobenzylidene)-1,2-propanediamine (Ald3) reacted with MO(CO)6 to give the respective cis-[(Ald)Mo(CO)4] complexes. N,N'-bis-(4-N,N-dimethylaminobenzylidene)1,3-propanediamine, in spite of comparatively poor reactivity, gave analogous tetracarbonyl, but its 1,4-butanediamine and 1,6-hexanediamine analogues did not give similar derivatives. Ald1-Ald3 after reaction with [(Ph3P)Mo(CO)5] gave corresponding aldimine bridged dinuclear [(Ph3P)(CO)4Mo(mu-Ald)Mo(CO)4(Ph3P)]. Cis-[(Ald)Mo(CO)4] gave [(Ald) Mo(CO)3X2] when reacted with X2 (X = Br or I), but produced [(Ald)MoCl4] after reaction with chlorine. NO reacted with tetracarbonyls to yield a mixture of unusual [(NO)(Ald) MO(CO)2(NO2)] and [(NO)2(Ald)Mo(NO2)2], but NOCl yielded only [(Ald) MO(CO)2(NO)Cl].

  DOI：

  10.1016/s0277-5387(00)83018-1