[([9]aneS3)Ru(pyrazine)2Cl])PF6 | 391953-21-2

• 英文名称: [([9]aneS3)Ru(pyrazine)2Cl])PF6
• CAS: 391953-21-2
• 化学式: C₁₄H₂₀ClN₄RuS₃*F₆P
• 分子量: 622.025
• InChiKey: SOVZKIBHAICSJA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡嗪 、 ammonium hexafluorophosphate 、 [(1,4,7-trithiacyclononane)Ru^II(DMSO)Cl₂] 、 水 以 乙醇 、 水 为溶剂， 以45%的产率得到[([9]aneS3)Ru(pyrazine)2Cl])PF6
  参考文献：
  名称：

  Building blocks for self-assembly: half-sandwich complexes of the [Ru([9]aneS3)]2+ metal center

  摘要：

  The X-ray crystal structure of the complex [([9]aneS(3))Ru(PhCN)(3)][PF6] (1) is reported. The metal coordination geometry of this structure is compared to that of the previously reported, [([9]aneS(3))Ru(py)(3)][PF6](2). This comparison clarifies conditions required for the successful synthesis of suitable, structurally robust building blocks for the future synthesis of higher order oligomeric structures. As a first approach to this strategy, the synthesis, and physical properties, of several appropriately functionalised half-sandwich complexes of the [Ru([9]aneS(3))](2+) metal center are reported. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00616-8