[Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-oxo)(μ-peroxo)] | 845254-36-6

• 英文名称: [Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-oxo)(μ-peroxo)]
• CAS: 845254-36-6
• 化学式: C₃₄H₄₀Fe₂N₆O₇
• 分子量: 756.422
• InChiKey: OIUSFOPWFWZEQR-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-oxo)(μ-peroxo)] 在 HClO₄ 作用下， 生成 [Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-hydroxo)(μ-peroxo)](1+)
  参考文献：
  名称：

  Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins

  摘要：

  (mu-Hydroxo or oxo)(mu-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(mu-OH or mu-O)(mu-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.

  DOI：

  10.1021/ja045594a
• 作为产物：
  描述：

  [Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-hydroxo)(μ-peroxo)](OTf) 在 triethyl amine 作用下， 以 甲醇 为溶剂， 生成 [Fe2(N,N-bis(6-methyl-2-pyridylmethyl)-3-aminopropionate)2(μ-oxo)(μ-peroxo)]
  参考文献：
  名称：

  Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins

  摘要：

  (mu-Hydroxo or oxo)(mu-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(mu-OH or mu-O)(mu-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.

  DOI：

  10.1021/ja045594a