([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])n | 173096-73-6

• 英文名称: ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])n
• 英文别名: ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])(.)
• CAS: 173096-73-6；173096-72-5
• 化学式: C₂₄H₃₃Cl₂CrMoP₂
• 分子量: 602.316
• InChiKey: FSWOYXRQZXEKOB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])n 在 4-pyridinecarbaldehyde 作用下， 以 甲苯 为溶剂， 生成 ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])(..+)
  参考文献：
  名称：

  Metal .pi. Complexes of Benzene Derivatives. 46. Communication between Chromium(I) and Molybdenum(III) in the Hetera[3]metallocyclophane {[(Me2P-.eta.6-C6H5)2Cr](Pri-.eta.5-C5H4)MoCl2}+.bul..bul.

  摘要：

  The binuclear radical complex 7(+) has been synthesized and studied by cyclic voltammetry; the redox couple 7(.)/7(..+) is reversible. During the course of the oxidation, the isotropic, fluid solution EPR signal of 7(.) is replaced by the rigid solution triplet EPR spectrum of 7(..+). The only intermetallic communication, detectable by EPR, consists in electron-electron spin-spin interaction in 7(..+). Its origin is essentially dipolar.

  DOI：

  10.1021/ic00130a029
• 作为产物：
  描述：

  {tetrachloro(η-isopropylcyclopentadienyl)molybdenum} 、 bis(dimethylphosphano-η(6)-benzene)chromium 在 sodium amalgam 作用下， 以 甲苯 为溶剂， 生成 ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])n 、 ([(Me2P-η(6)-C6H5)2Cr][(Pr(i)-η(5)-C5H4)MoCl2])n
  参考文献：
  名称：

  Metal .pi. Complexes of Benzene Derivatives. 46. Communication between Chromium(I) and Molybdenum(III) in the Hetera[3]metallocyclophane {[(Me2P-.eta.6-C6H5)2Cr](Pri-.eta.5-C5H4)MoCl2}+.bul..bul.

  摘要：

  The binuclear radical complex 7(+) has been synthesized and studied by cyclic voltammetry; the redox couple 7(.)/7(..+) is reversible. During the course of the oxidation, the isotropic, fluid solution EPR signal of 7(.) is replaced by the rigid solution triplet EPR spectrum of 7(..+). The only intermetallic communication, detectable by EPR, consists in electron-electron spin-spin interaction in 7(..+). Its origin is essentially dipolar.

  DOI：

  10.1021/ic00130a029