trans-(benzothiazole-κN)(3-benzylbenzothiazolin-2-ylidene)dibromidopalladium(II) | 1225031-02-6

• 英文名称: trans-(benzothiazole-κN)(3-benzylbenzothiazolin-2-ylidene)dibromidopalladium(II)
• CAS: 1225031-02-6
• 化学式: C₂₁H₁₆Br₂N₂PdS₂
• 分子量: 626.731
• InChiKey: FXGPJBATMBPTLJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  苯并噻唑 、 [PdBr(3-benzylbenzothiazolin-2-ylidene)]₂ 以 二氯甲烷 为溶剂， 以83%的产率得到trans-(benzothiazole-κN)(3-benzylbenzothiazolin-2-ylidene)dibromidopalladium(II)
  参考文献：
  名称：

  Benzothiazolin‐2‐ylidene and Azole Mixed‐Ligand Complexes of Palladium

  摘要：

  AbstractA series of mixed‐ligand, mononuclear complexes trans‐[PdX2(NSHC)(azole)] [NSHC = N,S‐heterocyclic carbene; azole = imidazole, 1‐(2,4,6‐trimethylphenyl)‐1H‐imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X‐ray single‐crystal diffraction. These complexes catalyse the sp2–sp3 cross‐coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900447