4,4-dimethoxy-1,3,5,7-tetramethyl-2,6-diethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene | 1219485-11-6

• 英文名称: 4,4-dimethoxy-1,3,5,7-tetramethyl-2,6-diethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene
• 英文别名: 2,6-diethyl-4,4-dimethoxy-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene；1,3,5,7-tetramethyl-2,6-diethyl-8-phenyl-4,4'-dimethoxy-bora-3a,4a-diaza-s-indacene
• CAS: 1219485-11-6
• 化学式: C₂₅H₃₃BN₂O₂
• 分子量: 404.36
• InChiKey: JUBPIPPYWNWBDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4,4'-diethyl-3,3',5,5'-tetramethyl-6-phenylpyrromethene 以 甲醇 、 甲苯 为溶剂， 生成 4,4-dimethoxy-1,3,5,7-tetramethyl-2,6-diethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene
  参考文献：
  名称：

  Cl-BODIPYs: a BODIPY class enabling facile B-substitution

  摘要：

  与相应的 F-BODIPYs 相比，Cl-BODIPYs 能在无气无湿的条件下以高产率从二吡喃中合成，而且极易在硼上发生取代反应，从而为硼官能化 BODIPYs 开辟了一条新途径。

  DOI：

  10.1039/c1cc16351e

文献信息

• Synthesis and photolysis of new BODIPY derivatives with chelated boron centre
  作者：Sherif S. Ragab

  DOI：10.1142/s1088424621500516

  日期：2021.9

  New borondipyromethene (BODIPY) derivatives chelated at the boron centre with different catecholate and salicylate ligands were synthesized via substituting the fluoride atoms with the aid of aluminum chloride that activates the boron-fluoride bond for substitution. The photophysical properties of the novel BODIPYs were investigated by normalized UV-vis absorption as well as the fluorescence emission

  合成了在硼中心与不同儿茶酸和水杨酸配体螯合的新型硼二吡咯 (BODIPY) 衍生物通过在氯化铝的帮助下取代氟化物原子，氯化铝激活硼-氟化物键以进行取代。通过归一化的紫外-可见吸收以及荧光发射光谱研究了新型 BODIPY 的光物理性质。此外，还计算了螯合BODIPYs的荧光量子产率，并研究了水杨酸盐衍生物的紫外线照射。
• Conversion of 4,4-Difluoro-4-bora-3a,4a-diaza-<i>s</i>-indacenes <b>(</b><i>F</i>-BODIPYs) to Dipyrrins with a Microwave-Promoted Deprotection Strategy
  作者：Sarah M. Crawford、Alison Thompson

  DOI：10.1021/ol902908j

  日期：2010.4.2

  4,4-Difluoro-4-bora-3a,4a-diaza-s-indacenes (F-BODIPYs) have been deprotected to give the corresponding free-base dipyrrins by heating a solution of the F-BODIPY In tert-butanol under 600 W of microwave irradiation in the presence of 6 equiv of potassium tert-butoxide for 40 min at 92 degrees C. Investigations of BODIPY modification at the meso position have also been undertaken and a meso-butyl product has been isolated.