Cp(CO)2MnSnCl2(thf) | 1078725-13-9

• 英文名称: Cp(CO)2MnSnCl2(thf)
• 英文别名: (CO)2(cyclopentadienyl)MnSnCl2(thf)
• CAS: 1078725-13-9
• 化学式: C₁₁H₁₃Cl₂MnO₃Sn
• 分子量: 437.776
• InChiKey: YGPWLVPMNOJWRS-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  Cp(CO)2MnSnCl2(thf) 以 neat (no solvent) 为溶剂， 生成 lambda~2~-Stannane--manganese (1/2)
  参考文献：
  名称：

  Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)

  摘要：

  Differential scanning calorimetry and thermogravimetry are used to study the thermolysis of following complexes: (Acac)(2)Sn(N-3)Cl (1); (Acac)(2)SnCl2 (2); (CO)(5)MSn(Acac)(2) with M = Cr (3) or W ((4)), (CO)(5)MSnCl2(thf) with M = Cr (5), Mo (6), or W (7)), (CH3)(4)N(CO)(5)MSnCl3 with M = Mo (8) or W ((9)), (CO)(2)MnCpSnCl2(thf) (10)); and (CO)(5)MSn(SCN)(2) with M = Cr (11) or W (12). The phase composition of the solid thermolysis products of compounds 1-5 and 7-12 is determined by X-ray powder diffraction. Thermolysis schemes are suggested.

  DOI：

  10.1134/s0036023607070200