[(C5H5)Ti(NP(C(CH3)3)3)CH3(P(p-MeC6H4)3)][(CH3B(C6F5)3)] | 848874-21-5

• 英文名称: [(C5H5)Ti(NP(C(CH3)3)3)CH3(P(p-MeC6H4)3)][(CH3B(C6F5)3)]
• CAS: 848874-21-5
• 化学式: C₁₉H₃BF₁₅*C₃₉H₅₆NP₂Ti
• 分子量: 1175.73
• InChiKey: JQXZINXUQTVWEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  CpTi(NPt-Bu3)Me2 、 三(五氟苯基)硼烷 、 三对苯甲基膦 以 二氯甲烷 为溶剂， 以87%的产率得到[(C5H5)Ti(NP(C(CH3)3)3)CH3(P(p-MeC6H4)3)][(CH3B(C6F5)3)]
  参考文献：
  名称：

  Cationic Methyl- and Chlorotitanium Phosphinimide Complexes

  摘要：

  A variety of donor-stabilized cationic complexes of the form [Cp(NPt-Bu-3)TiMe(L)] [MeB(C6F5)(3)] and [Cp(NPt-Bu-3)TiMe(L)] [B(C6F5)(4)] (L = Py, 4-EtPy, 4-t-BuPy, NC5H4NMe2, PMe3, Pn-Bu-3, PPh3, P(p-MeC6H4)(3)) have been prepared and characterized. Prolonged storage in CH2Cl2 solution resulted in chloride for methyl exchange to afford species of the form [CpTi(NPt-Bu-3)Cl(L)] [B(C6F5)(4)], [{CpTi(NPt-Bu-3)Me}(2)(mu-Cl)] [B(C6F5)(4)], and [CpTi(NPt-Bu-3)(mu-Cl)](2)[MeB(C6F5)(3)](2). The byproduct salt [(o-MeC6H4)(3)PCH2Cl] [B(C6F5)(4)] was obtained from reactions employing the sterically demanding donor phosphine P(o-MeC6H4)(3), suggesting transient generation of the cation [CpTi(NPt-Bu-3)Cl(CH2Cl2)](+). Analogous reactivity was not seen in C6H5Cl, although the species [{CpTi(NPt-Bu-3)Me}(2)(mu-Me)] [B(C6F5)(4)] could be formed in this solvent. The isolated zwitterionic complex TiCp(NPt-Bu-3)Me(mu-MeB(C6F5)(3)) readily performs insertion chemistry into the Ti-methyl bonds with diisopropylcarbodiimide and diphenylacetylene substrates to afford the cationic species [CpTi(NPt-Bu-3)((Ni-Pr)(2)CMe)] [MeB(C6F5)(3)], [TiCp(NPt-Bu-3)(PhCCPh(Me))] [MeB(C6F5)(3)], and [TiCp(NPt-Bu-3)(PhCCPh(Me))(PMe3)] [MeB(C6F5)(3)]. The implications of this chemistry are considered.

  DOI：

  10.1021/om0492202