tetrachloro[4,4'-bis(8,10-dimethyl-1,3,7,11,15-pentaazacyclohexadeca-7,11-diene-1-yl)-biphenyl]dicopper(II) | 183385-41-3

• 英文名称: tetrachloro[4,4'-bis(8,10-dimethyl-1,3,7,11,15-pentaazacyclohexadeca-7,11-diene-1-yl)-biphenyl]dicopper(II)
• 英文别名: tetrachloro[1,1'-phenylbis(1,3,7,11,15-pentaazacyclohexadecane-8,10-dimethyl-7,10-diene)]dicopper(II)
• CAS: 183385-41-3
• 化学式: C₃₈H₆₀Cl₄Cu₂N₁₀
• 分子量: 925.865
• InChiKey: RSSDBLCLZANJMB-PRKOADPOSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 copper(II) choride dihydrate 、 1,3-丙二胺 、 乙酰丙酮 、 联苯胺 以 甲醇 为溶剂， 以75%的产率得到tetrachloro[4,4'-bis(8,10-dimethyl-1,3,7,11,15-pentaazacyclohexadeca-7,11-diene-1-yl)-biphenyl]dicopper(II)
  参考文献：
  名称：

  Synthesis and Spectroscopic Studies of Bis(Macrocyclic) Dimetal(II) Complexes Based on 14–18 Membered Pentaaza Units

  摘要：

  Bis(macrocyclic) binuclear transition metal complexes [M2LCl4] [M = Fe(II), Co(II), Ni(II), Cu(II) and Zn(II); L = L-1-L-6, have been synthesised by the template condensation reaction of ethylenediamine or 1,3-diaminopropane with formaldehyde, benzidine and acetylacetone or dibenzoyl methane or phthalaldehyde in 4:4:1:2:2 molar ratio. All prepared complexes have been characterized by elemental analyses, IR, H-1 NMR, EPR and UV/VIS and conductivity data as well as magnetic susceptibility measurements. An octahedral geometry is suggested for all complexes.

  DOI：

  10.1080/00945719809351659

文献信息

• Shakir, Mohammad; Mohamed, Ajax K.; Varkey, Saji P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1996, vol. 35, # 11, p. 935 - 939
  作者：Shakir, Mohammad、Mohamed, Ajax K.、Varkey, Saji P.、Nasman, Omar S. M.

  DOI：——

  日期：——