cis-[Pd(II)(pyridinecarboxaldimine-3,5-C6H3(CF3)2)Cl2] | 773859-89-5

• 英文名称: cis-[Pd(II)(pyridinecarboxaldimine-3,5-C6H3(CF3)2)Cl2]
• CAS: 773859-89-5
• 化学式: C₁₄H₈Cl₂F₆N₂Pd
• 分子量: 495.547
• InChiKey: MWKDHXIISPWICD-UCRWNYPZSA-L

反应信息

• 作为产物：
  描述：

  pyridinecarboxaldimine-3,5-C6H3(CF3)2 、 [PdCl2(cis-cyclooctene)]2 以 二氯甲烷 为溶剂， 以60%的产率得到cis-[Pd(II)(pyridinecarboxaldimine-3,5-C6H3(CF3)2)Cl2]
  参考文献：
  名称：

  Synthesis, characterization, and cytotoxicities of palladium(II) and platinum(II) complexes containing fluorinated pyridinecarboxaldimines

  摘要：

  Condensation of 2-pyridinecarboxaldehyde with several primary amines containing fluorine groups gave the corresponding pyridinecarboxaldimines (N-N'). Addition of these ligands to [MCl2(coe)](2) (M = Pd, Pt; coe = cis-cyclooctene) gave complexes of the type cis-MCl2(N-N') [Pd (3) Pt (4)] in moderate to high yields. All palladium and platinum complexes were examined for their potential cytotoxicities against OV2008 (human ovarian carcinoma) and the analogous cisplatin-resistant C13. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.06.013