| 1204193-18-9

• CAS: 1204193-18-9
• 化学式: C₂₂H₁₅BBrClF₂N₂
• 分子量: 471.539
• InChiKey: YVYBOIRAJUBMNI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  3,5-dichloro-8-(4'-bromophenyl)-4,4-difluoro-4-bora-3a,4a-indacene 、 4-甲苯硼酸 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 0.5h， 以56%的产率得到
  参考文献：
  名称：

  Versatile synthetic methods for the engineering of thiophene-substituted Bodipy dyes

  摘要：

  Novel thienyl-borondiazadipyrromethene (Bodipy) dyes have been prepared using boronic acids or boronate reagents as cross-coupling mediators. A key dichloro/bromo-Bodipy starting material appears to be a useful starting material for such coupling reactions, enabling the synthesis of various symmetrically and unsymmetrically substituted thienyl-dyes. An alternative means of introducing thienyl substituents is through Knoevenagel substitution in the 3 and 5 positions of Bodipy by reaction with a formyl-functionalized thiophene derivative, resulting in systems of extended delocalization. All these Bodipy derivatives are stable and exhibit pronounced fluorescence on irradiation in the S-0 -> S-1 transition. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.09.163