| 449147-26-6

• CAS: 449147-26-6
• 化学式: C₂₀H₃₂S₂Ti
• 分子量: 384.486
• InChiKey: DLDXHZJFWVABJN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  环戊二烯钛 、 二戊基二硫醚 以 not given 为溶剂， 以67%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of Cp2Ti-containing organometallics via in situ oxidative-addition of ‘Cp2Ti’ intermediate.

  摘要：

  A simple and convenient route for synthesizing CP2Ti-containing compounds (RS)(2)TiCP2 (1, R = l-C10H7; 2, R = CH2-CHCH2; 3, R=n-C5H11; 4. R=CH2CO2Me; 5, R=CH2CO2Et; 6, R=(eta(5)-C5H5)Fe(eta(5)-C5H4CH2)) and [eta(2)-OC(Ph)=C(h)O]ToCp(2) (7) has been developed. This route starts from Cp2TiCl2 and involves an in situ oxidative-addition of the intermediate 'titanocene' with corresponding RSSR and benzil. While 7 was previously prepared by another route, 1-6 and one starting material [(eta(5)-C5H5)Fe(eta(5)-C5H4CH2)](2)S-2 (8) are new and have been characterized by elemental analysis, IR and H-1-NMR spectroscopy, as well as by X-ray diffraction analysis for 1, 6 and 7. Furthermore, the electrochemical properties of 1-6 have been studied by cyclic voltammetry. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01413-9