| 503088-50-4

• CAS: 503088-50-4
• 化学式: C₄₆H₄₀Cl₂N₃O₂P₂Re
• 分子量: 985.903
• InChiKey: TWJPWWJOCMAEEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三苯基膦 、 四丁基高铼酸铵 、 乙腈 、 肼基苯甲酸甲酯 在 盐酸 作用下， 以 乙腈 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  A Mono-Diazenide Complex from Perrhenate:  Toward a New Core for Rhenium Radiopharmaceuticals

  摘要：

  A new method for the synthesis of low to intermediate oxidation state rhenium complexes containing a bifunctional ligand has been developed. Reaction of [ReO4](-) with substituted phenyllhydrazines and triphenylphosphine in acetonitrile in the presence of HCl allows the isolation of [ReCl2(NNC6H4-4-R)(NCCH3)(PPh3)(2)] (where R = OCH3, Cl, or CO2CH3). The substituted hydrazine acts as both a reductant and source of a monodentate diazenide ligand. The compounds have all been characterized in the solid state by X-ray crystallography and in the solution state by NMR, electrospray mass spectrometry, and HPLC. Cyclic voltammetry measurements show that the mono-diazenide complexes undergo a reversible oxidation.

  DOI：

  10.1021/ic025995w