| 265312-31-0

• CAS: 265312-31-0
• 化学式: C₂₄H₃₅Al₂N₃O₂
• 分子量: 451.524
• InChiKey: VALQFQUFFCAKMU-SVMGFSKTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (6E)-6-[[3-[3-[[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]amino]propylamino]propylamino]methylidene]cyclohexa-2,4-dien-1-one 、 三甲基铝 以 甲苯 为溶剂， 以99.2%的产率得到
  参考文献：
  名称：

  Bimetallic and cationic aluminum with N3O2 chelate ligands

  摘要：

  The ligands aminobis(N-ethylenesaricylidenimine) (SalenN(3)H(3)) and aminobis(N-propylenesalicylidenimine) (SalpenN(3)H(3)) were used to form the bimetallic complexes SaIenN(3)H{AlMe2}(2) (1), SalpenN(3)H{AlMe2}(2) (2), SalenN(3)H{AlMeCl}(2) (3) and SalpenN(3)H{AlMeCl} (4). When extracted in THF 3 and 4 redistribute to form the ionic compounds [SalenN(3)H{Al(THF)}](+) [AlMe2Cl2](-) (5) and [SalpenN(3)H{Al(THF)}](+) [AlMe2Cl2](-) (6). The compounds were characterized by Mp analyses, H-1-NMR and IR, and in the case of 2 and 6 by X-ray crystallography. Additionally, the potential of 5 and 6 to serve as propylene oxide polymerization catalysts was examined. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00575-6