trans-[Rh(CO)(1,8-diazabicyclo[5.4.0]undec-7-ene)(PPh3)2]ClO4 | 168563-24-4

• 英文名称: trans-[Rh(CO)(1,8-diazabicyclo[5.4.0]undec-7-ene)(PPh3)2]ClO4
• CAS: 168563-24-4
• 化学式: C₄₆H₄₆N₂OP₂Rh*ClO₄
• 分子量: 907.188
• InChiKey: WBDHMVMTIYYQQE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans-[Rh(CO)(phenylhydrazine)(PPh3)2]ClO4 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 以 not given 为溶剂， 生成 trans-[Rh(CO)(1,8-diazabicyclo[5.4.0]undec-7-ene)(PPh3)2]ClO4
  参考文献：
  名称：

  Rhodium complexes with 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu): crystal structure of trans-[Rh(CO)(dbu)(PPh3)2]ClO4

  摘要：

  Attempts to deprotonate co-ordinated phenylhydrazine in trans-[Rh(CO)(NH(2)NHPh)(PPh(3))(2)]ClO4, using 1,8-diazabicyclo[5,4.0]undec-7-ene (dbu), resulted in the displacement of the co-ordinated hydrazine to give trans-[Rh(CO)(dbu)(PPh(3))(2)]CIO4 which has been fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. Other rhodium (I) complexes containing dbu have also been prepared and characterised spectroscopically.

  DOI：

  10.1039/dt9950002861