[ZnCl2(2-bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol)] | 1341184-40-4

• 英文名称: [ZnCl2(2-bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol)]
• CAS: 1341184-40-4
• 化学式: C₁₁H₁₄BrCl₃N₂OZn
• 分子量: 441.898
• InChiKey: QAGNWXWOVVJKBW-HFUUWOKWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol 、 zinc(II) chloride 以 甲醇 为溶剂， 以52%的产率得到[ZnCl2(2-bromo-4-chloro-6-[(3-methylaminopropylimino)methyl]phenol)]
  参考文献：
  名称：

  Synthesis, Crystal Structures, and Antibacterial Activities of Schiff-Base Zinc(II) Complexes [ZnL¹Cl₂] and [ZnL²I₂]·0.5CH₃OH

  摘要：

  Reaction of N-methylpropane- 1,3-diamine with 3-bromo-5-chlorosalicylaldehyde and 3-ethoxysalicylaldehyde, respectively, in methanol, forms two new Schiff bases, 2-bromo-4-chloro-6-[(3-methylaminopropylimino) methyl] phenol (L-1) and 2-ethoxy-6-[(3-methylaminopropylimino) methyl] phenol (L-2). Two new halido-coordinated zinc(II) complexes, [(ZnLCl2)-Cl-1] ( 1) and [(ZnLI2)-I-2]center dot 0.5CH(3)OH ( 2), derived from the Schiff bases, have been prepared and characterized by single-crystal x-ray diffraction, Fourier-transform infrared (FT-IR), and elemental analysis. Complex ( 1) crystallizes in the monoclinic space group P21/c, with a = 17.0640(10) angstrom, b = 13.238(2) angstrom, c = 14.843(2) angstrom, beta = 100.888(3)degrees, V = 3292.6(7) angstrom(3), Z = 8. Complex (2) crystallizes in the monoclinic space group P2(1)/n, with a = 15.7238(5) angstrom, b = 14.6918(5) angstrom, c = 18.4250(6) angstrom, beta = 114.7590(10)degrees, V = 3865.1(2) angstrom(3), Z = 2. The Zn atom in each complex is coordinated by one imino N and one phenolic O atoms of a Schiff-base ligand, and by two halide atoms (Cl for 1, and I for 2), forming a tetrahedral geometry. The Schiff bases and the complexes were assayed for antibacterial activities.

  DOI：

  10.1080/15533174.2011.591332