bis[μ-Cl2-(2,6-diisopropylphenyl)amino-4-(2,6-diisopropylphenyl)iminatocopper(II)-3-nitro-2-pentene] | 327624-81-7

• 英文名称: bis[μ-Cl2-(2,6-diisopropylphenyl)amino-4-(2,6-diisopropylphenyl)iminatocopper(II)-3-nitro-2-pentene]
• CAS: 327624-81-7
• 化学式: C₅₄H₇₂Cl₂Cu₂N₆O₄
• 分子量: 1067.2
• InChiKey: FLUNMYMOFURUGE-KXXRYXAHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2-(2,6-diisopropylphenyl)amino-4-(2,6-diisopropylphenyl)imino-3-nitro-2-pentene 以 乙醇 为溶剂， 以60%的产率得到bis[μ-Cl2-(2,6-diisopropylphenyl)amino-4-(2,6-diisopropylphenyl)iminatocopper(II)-3-nitro-2-pentene]
  参考文献：
  名称：

  Magnetoactive binuclear copper(II) complexes based on β-aminovinylimines

  摘要：

  beta-Aminovinylimines containing bulky substituents at the donor nitrogen atoms and copper(II) chelates based on them were synthesized. The compounds were studied by single crystal and powder X-ray diffraction, EXAFS, NMR, EPR, and UV/Vis spectroscopy, and magnetochemistry. The complexes with halide bridges exhibit a ferromagnetic type of spin-spin interaction. The metal chelate containing a phenyl substituent in the gamma-position of the aminovinylimino ligand absorbs atmospheric oxygen in a methylene dichloride solution, which gives rise to a dimer with oxygen bridges exhibiting an anti ferromagnetic type of spin-spin interaction.

  DOI：

  10.1134/s1070328406040105

文献信息

• ——
  作者：A. I. Uraev

  DOI：10.1023/a:1026639327693

  日期：——