fac-MnBr(CO)3{(P(C6H4CH3)2O)2SiMe2} | 138026-03-6

• 英文名称: fac-MnBr(CO)3{(P(C6H4CH3)2O)2SiMe2}
• CAS: 138026-03-6
• 化学式: C₃₃H₃₄BrMnO₅P₂Si
• 分子量: 735.505
• InChiKey: ICOMSVMJJCUNRZ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  五羰基溴化锰(I) 、 以 甲苯 为溶剂， 以51%的产率得到fac-MnBr(CO)3{(P(C6H4CH3)2O)2SiMe2}
  参考文献：
  名称：

  Silylphosphinites and their complexation to manganese. Crystal structure of cis-MnBr(Br(CO)4[P(4-CH3C6H4)2OSiMe3]

  摘要：

  The new silylphosphinites, (4-CH3C6H4)2POSiMe3(L) and [(4-CH3C6H4)2PO]2SiMe2(L-L) have been synthesised along with the manganese complexes cis-MnBr(CO)4L, trans,mer-MnBr(CO)3L2 and fac-MnBr(CO)3(L-L). The results of a single crystal X-ray diffraction study of cis-MnBr(CO)4L are also reported.

  DOI：

  10.1016/0022-328x(91)86173-n