Ru(III)(2,2'-bipyridine)(CO)(CH3CN)Cl2(1+) | 147486-22-4

• 英文名称: Ru(III)(2,2'-bipyridine)(CO)(CH3CN)Cl2(1+)
• CAS: 147486-22-4
• 化学式: C₁₃H₁₁Cl₂N₃ORu
• 分子量: 397.226
• InChiKey: UPQMFQTVBJVCSN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cis-(Cl) [Ru(2,2'-bipyridine)(CO)(CH3CN)Cl2] 以 乙腈 为溶剂， 生成 Ru(III)(2,2'-bipyridine)(CO)(CH3CN)Cl2(1+)
  参考文献：
  名称：

  Photochemical reactivity of [RuII(L)(CO)2Cl2] and [Me4N] [RuII(L)(CO)Cl3] (L = 2,2′-bipyridine or 4,4′- di(isopropoxycarbonyl)-2,2′-bipyridine) in CH3CN and the redox properties of the resulting new complexes

  摘要：

  Photolysis of acetonitrile solutions of [RuII(LXCO)2Cl2] or [Me4N][RuII(L)(CO)Cl3] (L = 2,2'-bipyridine or 4,4'-di(isopropoxycarbonyl-2,2'-bipyridine) leads to the successive formation of the new complexes [Ru(L)(CO)(CH3CN)Cl2], [Ru(L)(CH3CN)2Cl2], and [Ru(L)(CH3CN)3Cl]+ by photosubstitution processes. However, [Ru(L)(CH3CN)2Cl2], unlike [Ru(L)(CO)(CH3CN)Cl2] and [Ru(L)(CH3CN)3Cl]+, cannot be obtained quantitatively with the complex having the unsubstituted 2,2'-bipyridine ligand. Moreover [Ru(L)(CH3CN)3Cl]+ cannot be produced at a significant rate for complexes with L = 4,4'-isopropoxycarbonyl-2,2'-bipyridine. The redox behaviour of all these compounds was studied by cyclic voltammetry at a platinum electrode, exhaustive electrolysis experiments, and UV-visible absorption spectroscopy.

  DOI：

  10.1016/0022-328x(93)83073-5