(azido{1,3-bis(2-pyridylimino)isoindolinato}nickel(II)) | 53575-90-9

• 英文名称: (azido{1,3-bis(2-pyridylimino)isoindolinato}nickel(II))
• CAS: 53575-90-9
• 化学式: C₁₈H₁₂N₈Ni
• 分子量: 399.037
• InChiKey: KUPKRHHROKPZIE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3-bis-(2-pyridylimino)isoindoline 在 sodium azide 作用下， 以 甲醇 、 正丁醇 为溶剂， 生成 (azido{1,3-bis(2-pyridylimino)isoindolinato}nickel(II))
  参考文献：
  名称：

  (1,3-Bis(2′-pyridylimino)isoindolinato)nickel(II) complexes of phenylcyanamido ligands: crystal structure, electronic absorption spectroscopy and solvent adduct studies

  摘要：

  Complexes of the formula Ni(L)X, where L=1,3-bis(2'-pyridylimino)isoindolinato and X = Cl, Br, N3, NCS, 2-Clpcyd, 4-Clpcyd, 2,3-Cl2pcyd, 2,6-Cl2pcyd, 2,4,5-Cl3pcyd and 2,3,5,6-Cl4pcyd, have been synthesized and characterized by elemental analysis, and IR, H-1 NMR and UV-Vis spectroscopies. A crystal structure determination of Ni(L)(2-Clpcyd) showed nickel in a distorted square planar coordination sphere of nitrogen donor atoms in which the phenylcyanamido ligand is coordinated to Ni(II) via the terminal nitrogen. The solvent coordination equilibria of Ni(L)(pcyd) complexes was also investigated and the results suggest that both electronic and steric factors play important roles in determining the stability of the solvated complex.

  DOI：

  10.1016/s0020-1693(00)83326-5