[Ni2(N,N'-propylenebis(3-formyl-5-tert-butylsalicylaldimine-2H)(NO3)(H2O)3]NO3 | 1353637-82-7

• 英文名称: [Ni2(N,N'-propylenebis(3-formyl-5-tert-butylsalicylaldimine-2H)(NO3)(H2O)3]NO3
• 英文别名: [Ni2(CH2(CH2NCH(C6H2)(O)(CHO)(tBu))2)(NO3)(H2O)3]NO3
• CAS: 1353637-82-7
• 化学式: C₂₇H₃₈N₃Ni₂O₁₀*NO₃
• 分子量: 743.998
• InChiKey: XPRAUQQYAVVEEU-GZMNROJWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 ,N’-propanebis(3-phormyl-5-tert-butyl-salicylaldimine) 、 水 以 乙醇 为溶剂， 以52%的产率得到[Ni2(N,N'-propylenebis(3-formyl-5-tert-butylsalicylaldimine-2H)(NO3)(H2O)3]NO3
  参考文献：
  名称：

  Dinickel(II) complex of N, N′-propylenebis(3-formyl-5-tert-butylsalicylaldimine): X-ray structural characterization and bio-relevant catalytic activity

  摘要：

  A novel dinuclear nickel(II) complex, [Ni2L(NO3)(H2O)(3)]NO3 (where L is a 'side-off' compartmental ligand obtained by [1 + 2] condensation of 1,3-diaminopropane and 2,6-diformyl-4-tert-butylphenol) has been synthesized and characterized by routine physicochemical techniques as well as by X-ray single crystal structure analysis. Structure determination reveals that the two nickel ions, separated by 3.0824(9) angstrom, occupy the N2O2 and O-4 compartments of the Schiff base ligand. The immediate coordination environment of each nickel ion is octahedral and the species adopts an umbrella bowed conformation. The catalytic activity of the complex for the oxidation of 3,5-di-tert-butylcatechol to the corresponding o-quinone in methanol solvent has been studied by UV-vis spectroscopic technique. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.10.041