(N-(3-(2-pyridylmethoxy)propyl)-N,N-bis(2-pyridylmethyl)amine)chlorozinc(II) perchlorate | 1305223-31-7

• 英文名称: (N-(3-(2-pyridylmethoxy)propyl)-N,N-bis(2-pyridylmethyl)amine)chlorozinc(II) perchlorate
• CAS: 1305223-31-7
• 化学式: C₂₁H₂₄ClN₄OZn*ClO₄
• 分子量: 548.741
• InChiKey: GHIXCNOLLVOHIG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-[3-(2-pyridylmethyloxy)-1-propyl]-N,N-bis(2-pyridylmethyl)amine 、 sodium perchlorate 、 zinc(II) chloride 以 甲醇 为溶剂， 以42%的产率得到(N-(3-(2-pyridylmethoxy)propyl)-N,N-bis(2-pyridylmethyl)amine)chlorozinc(II) perchlorate
  参考文献：
  名称：

  Intramolecular ether oxygen coordination in the zinc complexes with dipicolylamine (DPA)-derived ligands

  摘要：

  The ether oxygen coordination to the zinc center in the complexes with dipicolylamine (DPA)-derived ligands, N-(2-methoxyethyl)-N, N-bis(2-pyridylmethyl) amine (L), N-(3-methoxypropyl)-N, N-bis(2-pyridylmethyl) amine (L'), and N-{3-(2-pyridylmethyloxy)propyl}-N, N-bis(2-pyridylmethyl) amine (L-Py) has been discussed. Upon chelation of the oxygen atom, L forms a five-membered chelate ring with respect to the 2-aminoethyl ether moiety whereas L' forms a six-membered chelate in 3-aminopropyl ether unit. This difference was highlighted by the crystal structures of ZnCl2 complexes, in which [Zn(L)Cl-2] (1) exhibited ether oxygen coordination but [Zn(L')Cl-2] (2) had the ether oxygen non-coordinated. The terminal pyridyl group of L-Py facilitates the ether oxygen atom coordination via a metal binding from the basal plane trans to the aliphatic nitrogen. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.022