tricarbonylchlorobis(tri-p-tolylphosphine)rhenium | 153588-67-1

• 英文名称: tricarbonylchlorobis(tri-p-tolylphosphine)rhenium
• CAS: 153588-67-1
• 化学式: C₄₅H₄₂ClO₃P₂Re
• 分子量: 914.434
• InChiKey: BJTDHTBNXMDPGZ-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 三对苯甲基膦 以 not given 为溶剂， 生成 tricarbonylchlorobis(tri-p-tolylphosphine)rhenium
  参考文献：
  名称：

  Electronic emission and absorption spectroscopy of the rhenium complexes Re(CO)3Cl(phosphine)2

  摘要：

  The compounds Re(CO)3Cl(L)2, L = triphenylphosphine, tri-p-tolyphosphine, and Re(CO)3-Cl(L'), L' = 1,2-bis(diethylphosphinoethane) are luminescent in solution and in crystalline form when excited between 351 nm and 514 nm at temperatures ranging from 10 K to room temperature. The absorption spectra contain a weak (E approximately 10 M-1 cm-1) band in the visible region of the spectrum between 400 and 500 nm. The lowest energy transition giving rise to these spectroscopic features is assigned to a d-d transition.

  DOI：

  10.1007/bf00816407