[Fe((C5H4(OC2H4)2OCH2)2C5H3N)Na]B(C6H3-3,5-(CF3)2)4 | 1257224-99-9

• 英文名称: [Fe((C5H4(OC2H4)2OCH2)2C5H3N)Na]B(C6H3-3,5-(CF3)2)4
• 英文别名: [Fe((C5H4(OC2H4)2OCH2)2C5H3N)Na]BARF
• CAS: 1257224-99-9
• 化学式: C₂₅H₃₁FeNNaO₆*C₃₂H₁₂BF₂₄
• 分子量: 1383.58
• InChiKey: DPWFZVSRWOFHSR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 not given 为溶剂， 生成 [Fe((C5H4(OC2H4)2OCH2)2C5H3N)Na]B(C6H3-3,5-(CF3)2)4
  参考文献：
  名称：

  Synthesis, structure and properties of the macrocyclic ferrocenophanes with cyclopentadienyl ligands tethered by oligo(ethylene glycol) chain

  摘要：

  Cyclization reactions of Fe{C(5)H(4)OCH(2)(CH(2)OCH(2))(n)CH(2)OTs} 2 (n = 1, 2) with C(6)H(4)-1,2-(OH)(2),C(6)H(4)-1,3-(OH)(2), and Fe(C(5)H(4)OAc)(2) under basic conditions yield the corresponding macrocyclic 1,1'-ferrocenophanes. The ferrocenophane having a pyrido-crown ether structure was also synthesized. These ferrocenophanes were characterized by X-ray crystallography and NMR spectroscopy. Cyclic voltammograms of the ferrocenophanes exhibited reversible redox peaks assigned to the oxidation and reduction of the ferrocene unit. The macrocyclic pyrido-containing ferrocenophane forms pseudorotaxane with [NH(2){(CH(2))(9)Me}(2)]BARF (BARF = B{C(6)H(3)-3,5-(CF(3))(2)}(4)) in CDCl(3). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.07.028