μ-[cyclobis(1,4-phenylene-4,4'-diyl diethylphosphoramidite)]bis[acetylacetonatocarbonylrhodium(I)] | 370098-37-6

• 英文名称: μ-[cyclobis(1,4-phenylene-4,4'-diyl diethylphosphoramidite)]bis[acetylacetonatocarbonylrhodium(I)]
• CAS: 370098-37-6
• 化学式: C₃₂H₄₂N₂O₁₀P₂Rh₂
• 分子量: 882.451
• InChiKey: FRUZGJYTVIZZKP-ZAMFMGCBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  acetylacetonatodicarbonylrhodium(l) 、 cyclobis(1,4-phenylene-4,4'-diyl diethylphosphoramidite) 以 二氯甲烷 为溶剂， 以84%的产率得到μ-[cyclobis(1,4-phenylene-4,4'-diyl diethylphosphoramidite)]bis[acetylacetonatocarbonylrhodium(I)]
  参考文献：
  名称：

  摘要：

  The first representatives of linear phosphocyclophanes were prepared starting from hydroquinone or 4,4'-dihydroxybiphenyl and phosphorous triamides. The reaction course is influenced by the structures of the aromatic diol and alkyl substituents in the phosphamide moiety. The phosphorus atom readily enters redox reactions and complexation. The complexing power of the aromatic fragments of the synthesized molecules is lower than that of classical p-cyclophanes.

  DOI：

  10.1023/a:1012357001662