Fe(III)protoporphyrin(CN)2 | 41127-52-0

• 英文名称: Fe(III)protoporphyrin(CN)2
• CAS: 41127-52-0
• 化学式: 2CN*C₃₄H₃₂FeN₄O₄
• 分子量: 668.535
• InChiKey: DFRXHKAEKSSRQH-HXFTUNQESA-N

反应信息

• 作为产物：
  描述：

  iron(III)protoporphyrin IX chloride 在 氰化钠 作用下， 生成 Fe(III)protoporphyrin(CN)2
  参考文献：
  名称：

  电子和振动独立的原卟啉IX乙烯基的紫外线共振拉曼证据

  摘要：

  We have examined the protoporphyrin IX (PP) peripheral vinyl C=C stretching 220-nm-excited resonance Raman cross sections, depolarization ratios, and vinyl stretching frequencies. The depolarization ratio of 0.33 observed for the bis(cyanide) complexes of both PP and a monovinylporphyrin derivative indicates that the enhancement of the vinyl vibration is likely in both cases to be dominated by a single tensor component in a manner similar to that for the C=C stretch of simpler olefins. The data suggest that the two peripheral vinyl groups are vibrationally uncoupled.

  DOI：

  10.1021/j100196a013