2-(2-{[bis(2-ethylhexyl)carbamoyl]methoxy}phenoxy)-N,N-bis(2-ethylhexyl)acetamide | 1400776-65-9

• 英文名称: 2-(2-{[bis(2-ethylhexyl)carbamoyl]methoxy}phenoxy)-N,N-bis(2-ethylhexyl)acetamide
• 英文别名: 2-[2-[2-[bis(2-ethylhexyl)amino]-2-oxoethoxy]phenoxy]-N,N-bis(2-ethylhexyl)acetamide
• CAS: 1400776-65-9
• 化学式: C₄₂H₇₆N₂O₄
• 分子量: 673.076
• InChiKey: NDANQFDOCDDUEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  48
• 可旋转键数：
  30
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-氯-N,N-二(2-乙基己基)乙酰胺 、 邻苯二酚 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 18.0h， 以95%的产率得到2-(2-{[bis(2-ethylhexyl)carbamoyl]methoxy}phenoxy)-N,N-bis(2-ethylhexyl)acetamide
  参考文献：
  名称：

  Bis-(2-ethylhexyl) carbamoyl methoxy phenoxy-bis-(2-ethylhexyl) acetamide [BenzoDODA]—first selective extractant for plutonium(IV) recovery (SEPUR) from acidic media

  摘要：

  A novel extractant, namely, Benzodioxodiamide (BenzoDODA) has been synthesized and evaluated for its extraction behaviour towards plutonium and other elements present in the spent nuclear fuel. High separation factors for plutonium over other elements were observed, indicating the high selectivity of the extractant for plutonium. The extractant is quite promising for the selective separation of plutonium from dissolver solution and various acidic waste streams. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.07.124