Rh(1,5-cyclooctadiene)[κ(2)-(hydrobis(3-phenyl-5-isopropylpyrazolyl)(3,5-dimethylpyrazolyl)borate)] | 690635-94-0

• 英文名称: Rh(1,5-cyclooctadiene)[κ(2)-(hydrobis(3-phenyl-5-isopropylpyrazolyl)(3,5-dimethylpyrazolyl)borate)]
• CAS: 690635-94-0
• 化学式: C₃₇H₄₆BN₆Rh
• 分子量: 688.529
• InChiKey: OEKUYRIUTKJHDK-GHDUESPLSA-N

反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 sodium hydro(3,5-dimethylpyrazolyl)bis(5-isopropyl-3-phenylpyrazolyl)borate 以 甲苯 为溶剂， 以85%的产率得到Rh(1,5-cyclooctadiene)[κ(2)-(hydrobis(3-phenyl-5-isopropylpyrazolyl)(3,5-dimethylpyrazolyl)borate)]
  参考文献：
  名称：

  Complexes of heteroscorpionate trispyrazolylborate ligands. Part XII. Variable hapticity of hydrobis(3-phenyl-5-isopropylpyrazolyl)(3,5-dimethylpyrazolyl)borate in its rhodium(I) complexes with COD and NBD

  摘要：

  The structure of Tp"Rh(NBD) complex was determined by X-ray crystallography (Tp" = hydrobis(3-phenyl-5-isopropylpyrazolyl)(3,5-dimethylpyrazolyl)borate, NBD = 2,5-norbornadiene). The Tp" was found to be kappa(3) coordinated to rhodium(I). Two independent molecules of Tp"Rh(NBD) were found in triclinic crystals with Rh-N(pz) distances in the region of 2.113(3)-2.307(3) Angstrom. On the other hand the same Tp" ligand was demonstrated to be coordinated in kappa(2) fashion in Tp"Rh(COD) (COD = 1,5-cyclooctadiene) by variable temperature 1-D and 2-D H-1 NMR measurements. The intramolecular exchange between coordinated and uncoordinated 3-phenyl-5-isopropylpyrazolyl residues occurs with DeltaG(not equal) = 42.2 kJ/mol as it was calculated from the H-1 NMR studies. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.11.010