[η-C5H4CMe2PPhCrCl]2 | 714277-47-1

• 英文名称: [η-C5H4CMe2PPhCrCl]2
• CAS: 714277-47-1
• 化学式: C₂₈H₃₀Cl₂Cr₂P₂
• 分子量: 603.392
• InChiKey: VZRSIWXHHTUPFU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [η-C5H4CMe2PPhCrCl2(PMe2Ph)] 在 1,8-diazabicyclo(5.4.0)undec-7-ene 作用下， 以 not given 为溶剂， 生成 [η-C5H4CMe2PPhCrCl]2
  参考文献：
  名称：

  Phosphanylalkylcyclopentadienyl ligands: synthesis, molecular structures and catalytic properties of [{(η5-C5H4)CMe2PHR}CrCl2(PMe2Ph)] (R=Ph, )

  摘要：

  Li[(C5H4)CMe2PHPh] reacted with [CrCl3(THF)(3)] with formation of a mixture of products, among which only [{(eta(5)-C5H4)CMe2PPh}CrCl](2) (1) could be isolated. However, when [CrCl3(PMe2Ph)(3)] was treated with Li[(C5H4)CMe2PHR], the complexes [{(eta(5)-C5H4)CMe2PHR}CrCl2(PMe2Ph)] (R = Ph (2), Bu-t (3)) were obtained in moderate yield. Complexes 1 and 2 were characterised by X-ray crystallography, 1-3 by IR spectroscopy. In the solid state, a phosphanido-bridged dimer is observed for 1, while 2 and 3 are monomeric complexes without coordination of the phosphanyl group of the cyclopentadienyl ring. 2 and 3 were also characterised by mass spectrometry and NMR and UV-Vis spectroscopy, and their magnetic moments were determined. 2 and 3 were studied in the catalytic polymerisation of ethylene with methylalumoxane (MAO) as cocatalyst. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.02.011