[Cu(2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4 | 1208231-52-0

• 英文名称: [Cu(2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4
• 英文别名: [(dpephos)(2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)copper(I)]BF4
• CAS: 1208231-52-0
• 化学式: BF₄*C₅₉H₄₂CuN₄OP₂
• 分子量: 1035.31
• InChiKey: OVJYCGJMPBZTQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4 以 neat (no solvent) 为溶剂， 生成 铜(1+)四氟硼酸盐
  参考文献：
  名称：

  A Series of Cu ^I Complexes Containing 1,10‐Phenanthroline Derivative Ligands: Synthesis, Characterization, Photophysical, and Oxygen‐Sensing Properties

  摘要：

  AbstractFive novel copper(I) complexes with the general formula [Cu(dpephos)(NN)]BF4 {dpephos = bis[2‐(diphenylphosphanyl)phenyl] ether, NN = 2‐phenyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (pip, 1), 1‐ethyl‐2‐phenyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (epip, 2), 2‐(naphthalen‐1‐yl)‐1H‐imidazo[4,5‐f][1,10]phenanthroline (nip, 3), 1‐ethyl‐2‐(naphthalen‐1‐yl)‐1H‐imidazo[4,5‐f][1,10]phenanthroline (enip, 4), 2‐(anthracen‐9‐yl)‐1‐ethyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (aeip, 5)} were rationally designed and synthesized, and these complexes were characterized by 1H NMR and IR spectroscopy and elemental analysis. X‐ray crystal‐structure analysis of 3 and 4 are also presented. Their photophysical properties at room temperature were examined by using a combination of cyclic voltammetry and electronic absorption spectroscopy. It was found that 1–4 display broad‐band emission in the solid state upon excitation at λ = 400 nm, and the emission maxima are located in the range 530–558 nm; the excited‐state lifetimes of these complexes are 8.24, 1.97, 6.99, and 2.43 μs, respectively. As a result, the emission intensity of complexes 1–4 is sensitive to oxygen concentration, and they display oxygen‐sensing properties after they are encapsulated into mesoporous silica MCM‐41 or SBA‐15.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900123
• 作为产物：
  描述：

  tetrakis(acetonitrile)copper(I)tetrafluoroborate 、 双(2-二苯基磷苯基)醚 、 2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline 以 二氯甲烷 为溶剂， 以83%的产率得到[Cu(2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4
  参考文献：
  名称：

  A Series of Cu ^I Complexes Containing 1,10‐Phenanthroline Derivative Ligands: Synthesis, Characterization, Photophysical, and Oxygen‐Sensing Properties

  摘要：

  AbstractFive novel copper(I) complexes with the general formula [Cu(dpephos)(NN)]BF4 {dpephos = bis[2‐(diphenylphosphanyl)phenyl] ether, NN = 2‐phenyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (pip, 1), 1‐ethyl‐2‐phenyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (epip, 2), 2‐(naphthalen‐1‐yl)‐1H‐imidazo[4,5‐f][1,10]phenanthroline (nip, 3), 1‐ethyl‐2‐(naphthalen‐1‐yl)‐1H‐imidazo[4,5‐f][1,10]phenanthroline (enip, 4), 2‐(anthracen‐9‐yl)‐1‐ethyl‐1H‐imidazo[4,5‐f][1,10]phenanthroline (aeip, 5)} were rationally designed and synthesized, and these complexes were characterized by 1H NMR and IR spectroscopy and elemental analysis. X‐ray crystal‐structure analysis of 3 and 4 are also presented. Their photophysical properties at room temperature were examined by using a combination of cyclic voltammetry and electronic absorption spectroscopy. It was found that 1–4 display broad‐band emission in the solid state upon excitation at λ = 400 nm, and the emission maxima are located in the range 530–558 nm; the excited‐state lifetimes of these complexes are 8.24, 1.97, 6.99, and 2.43 μs, respectively. As a result, the emission intensity of complexes 1–4 is sensitive to oxygen concentration, and they display oxygen‐sensing properties after they are encapsulated into mesoporous silica MCM‐41 or SBA‐15.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200900123

文献信息

• A phosphorescent copper(I) complex: Synthesis, characterization, photophysical property, and oxygen-sensing behavior
  作者：Caihong Wen、Guoquan Tao、Xinhua Xu、Xiaoqing Feng、Rongcheng Luo

  DOI：10.1016/j.saa.2011.04.067

  日期：2011.9

  In this paper, we report the synthesis, crystal structure, photophysical properties, and electronic nature of a phosphorescent Cu(I) complex of [Cu(Phen-Np)(POP)]BF4, where Phen-Np and POP stand for 2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline and bis(2-(diphenylphosphanyl)phenyl) ether, respectively. [Cu(Phen-Np)(POP)]BF4 renders a yellow phosphorescence peaking at 545 nm, with a long

  在本文中，我们报告了[Cu（Phen-Np）（POP）] BF4的磷光Cu（I）配合物的合成，晶体结构，光物理性质和电子性质，其中Phen-Np和POP代表2- （萘-1-基）-1H-咪唑并[4,5-f] [1,10]菲咯啉和双（2-（2-（二苯基膦基）苯基）醚。[Cu（Phen-Np）（POP）] 的黄色磷光在545 nm处达到峰值，激发态寿命为4.69μs。密度泛函计算表明该发射来自三重态金属到配体电荷转移的激发态。我们对[Cu（Phen-Np）（POP）] 和聚苯乙烯（PS）的复合纳米纤维进行电纺，以期探索将复合纳米纤维用作氧气传感材料的可能性。最终获得的平均直径约为300 nm的样品的最大灵敏度为7。由于纳米纤维膜的表面积与体积之比大，因此它对分子氧具有2的响应时间，而响应时间仅为7s。在这些样品中未检测到光致漂白。