[2-(1-(3,5-dimethylphenyl)-2-naphthyl)-4,5-dihydro-4,4-dimethyl-1,3-oxazole]selenenium(II) trifluoroacetate | 1508300-86-4

• 英文名称: [2-(1-(3,5-dimethylphenyl)-2-naphthyl)-4,5-dihydro-4,4-dimethyl-1,3-oxazole]selenenium(II) trifluoroacetate
• CAS: 1508300-86-4
• 化学式: C₂F₃O₂*C₂₃H₂₂NOSe
• 分子量: 520.41
• InChiKey: RGSLPMOEMXTLSQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [2-(1-(3,5-dimethylphenyl)-2-naphthyl)-4,5-dihydro-4,4-dimethyl-1,3-oxazole]selenenyl(II) bromide 、 silver trifluoroacetate 以 甲醇 为溶剂， 反应 2.0h， 以57%的产率得到[2-(1-(3,5-dimethylphenyl)-2-naphthyl)-4,5-dihydro-4,4-dimethyl-1,3-oxazole]selenenium(II) trifluoroacetate
  参考文献：
  名称：

  Synthesis of Selenenium Ions: Isolation of Highly Conjugated, pH-Sensitive 4,4′-Bis(methylimino)-1,1′-binaphthylene-5-diselenenium(II) Triflate

  摘要：

  The isolation of novel selenenium cations, stabilized by only one intramolecularly coordinating group (Se center dot center dot center dot N), is described. The electronic nature of the cations has been probed by calculating natural bonding orbital charges and Wiberg bond indices. [8-(Dimethylamino)-1-naphthyl]-selenenyl(II) triflate oxidizes in methanol via C-C coupling to give a novel blue-colored 4,4'-bis(methylimino)-1,1'-binaphthylene-5-diselenenium(II) triflate. The pH dependence of the color has been investigated.

  DOI：

  10.1021/om400460z