| 197729-31-0

• CAS: 197729-31-0；197808-73-4
• 化学式: C₃₈H₅₆Br₂P₂Pd₂
• 分子量: 947.458
• InChiKey: BOZFSGCTGREQAL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 2H-咪唑-2-亚基,1,3-二环己基-1,3-二氢- 以 甲苯 为溶剂， 以93%的产率得到bis(1,3-dicyclohexylimidazolin-2-ylidene)[o-(dicyclohexylphosphino)benzyl]palladium(II) bromide
  参考文献：
  名称：

  Synthesis and Characterization of N-Heterocyclic Carbene Phospha-Palladacycles and Their Properties in Heck Catalysis

  摘要：

  Palladacycles are among the most active catalyst systems for the Mizoroki-Heck reaction to date. We present N-heterocyclic carbene (NHC) substituted phospha-palladacycles as a new class of catalysts. This new type of palladacycles combines the advantageous stability of phospha-palladacycles with the steric demand and high a-donor strength of N-heterocyclic carbenes. In this work NHC-substituted phospha-palladacycles are tested in Heck catalysis. The activity of these catalysts allows the coupling of even aryl chlorides in good yields.

  DOI：

  10.1021/om049001g